My table won't align properly this link:

http://www.teampaulmitchellkarate.com/meet-the-team/

Can there be something im missing using the CSS/hspace vsapce?

I understand a lot of links are identical nevertheless its design I am worried about.

It is simply incorrect HTML syntax. There are several places with extra quotes prior to the word align ("align=)

A remedied version is http://jsbin.com/owehit/edit#html,live